This is my company car and I drive many miles, as part of my job, in it every day. I must say that this car is fairly uncomfortable. It is down to the driving position; there is little room for your legs (I am 6ft) and the steering wheel is too far to reach (only height adjustable) when you have adjusted the seat properly for your legs. The pedals are very small and close together- I was revving the engine whilst braking when I first got the car! The seats are fairly basic, but reasonably supportive. I wouldn't recommend buying this car if you regularly want to travel long distances.
The 8v 1.4 isn't especially quick (75bhp), but it is nippy enough around town- up to about 50mph- and is quick off the mark. The brakes aren't great and the pedal needs quite a lot of input. Steering is fine, if a little light, however the car does under steer quite badly when pushed.
I have owned a number of Peugeot's and VW's in the past, as with all my previous Peugeot's the cabin isn't especially well designed and the quality is lacking compared to a German marque, but usually the Pug has made up for this by being fun handling and pleasant to look at (205 or 306). Unfortunately, the 206 isn't much fun. Although the looks aren't all that bad.
I feel a bit unfair on the 206, as it isn't really designed for the millage I need to use it for. As a first time run-about or little town car, it's probably fine; easy to park, cheap to buy and fix, looks pleasant enough, loud stereo, fairly economical and can do the odd long journey- it cruises well enough at 80mph, it's just very noisy. But I can't recommend it for many motor way miles and it seriously disappoints as a drivers car compared to past Peugeot's.